Reactivity series periodic table3/24/2024 ![]() ![]() For example, a lone hydrogen atom has a single electron in its 1s orbital. To achieve one of these orders of stability, an atom reacts with another atom to stabilize both. Generally, electrons exist in orbitals that are the result of solving the Schrödinger equation for specific situations.Īll things (values of the n and m l quantum numbers) being equal, the order of stability of electrons in a system from least to greatest is unpaired with no other electrons in similar orbitals, unpaired with all degenerate orbitals half-filled and the most stable is a filled set of orbitals. Thermodynamically, a chemical reaction occurs because the products (taken as a group) are at a lower free energy than the reactants the lower energy state is referred to as the "more stable state." Quantum chemistry provides the most in-depth and exact understanding of the reason this occurs. The second meaning of reactivity (i.e., whether or not a substance reacts) can be rationalized at the atomic and molecular level using older and simpler valence bond theory and also atomic and molecular orbital theory. The half-life of such a species is another manifestation of its stability, but its reactivity can only be ascertained via its reactions with other species. For example, an isolated molecule of an electronically excited state of the oxygen molecule spontaneously emits light after a statistically defined period. The concept of stability should not be confused with reactivity. ![]() For example, the statement that "sodium metal is reactive" suggests that sodium reacts with many common reagents (including pure oxygen, chlorine, hydrochloric acid, and water), either at room temperature or when using a Bunsen burner. However, in all cases, reactivity is primarily due to the sub-atomic properties of the compound.Īlthough it is commonplace to make statements that "substance X is reactive," each substance reacts with its own set of reagents. In crystalline compounds, the crystalline form can also affect reactivity. In impure compounds, the reactivity is also affected by the inclusion of contaminants. For instance, grinding a sample to a higher specific surface area increases its reactivity. In pure compounds, reactivity is regulated by the physical properties of the sample. ![]() Reactivity then refers to the rate at which a chemical substance tends to undergo a chemical reaction in time. Restriction of the term to refer to reaction rates leads to a more consistent view. Hydrogen does not react with oxygen-even though the equilibrium constant is very large-unless a flame initiates the radical reaction, which leads to an explosion. In fact, the rate of reaction of alkali metals (as evidenced by their reaction with water for example) is a function not only of position within the group but also of particle size. For example, it is commonly asserted that the reactivity of alkali metals ( Na, K, etc.) increases down the group in the periodic table, or that hydrogen's reactivity is evidenced by its reaction with oxygen. Both factors are actually distinct, and both commonly depend on temperature. It appears to embody both thermodynamic factors and kinetic factors (i.e., whether or not a substance reacts, and how fast it reacts). Reactivity is a somewhat vague concept in chemistry. The term reactivity is related to the concepts of chemical stability and chemical compatibility. equilibrium point of the reaction (i.e., the extent to which all of it reacts), and.variety of substances with which it reacts,.The chemical reactivity of a substance can refer to the variety of circumstances (conditions that include temperature, pressure, presence of catalysts) in which it reacts, in combination with the: interacts with two or more other reactants to form two or more products.forms new substances by addition of atoms from another reactant or reactants, and.The chemical reactivity of a single substance (reactant) covers its behavior in which it: theories to predict and to account for these processes.experimental methods that are used to observe these processes, and.methodology that applies to the study of reactivity of chemicals of all kinds,.the systematic study of sets of reactions of these two kinds,.the chemical reactions of two or more substances that interact with each other,.the chemical reactions of a single substance,.In chemistry, reactivity is the impulse for which a chemical substance undergoes a chemical reaction, either by itself or with other materials, with an overall release of energy. JSTOR ( June 2016) ( Learn how and when to remove this template message).Unsourced material may be challenged and removed.įind sources: "Reactivity" chemistry – news Please help improve this article by adding citations to reliable sources. This article needs additional citations for verification. ![]()
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![]() ![]() They even have a move ordinarily learned by TM, or not at all! Examples include the ability to trade for Pokémon such as Gligar, Skarmory, Beldum and Smoochum.
Clapton driftin blues tablature3/21/2024 ![]() B7 gggg VV k VV V 32 I V V VV 0 3 4 2 3 V k aPR gVV VVV f V VVV T A B 0 0 1 0 1 2 0 2 3 0 0 1 0 0 1 0 0 1 0 0 1 3 A7 k V V VVV VVV V u 0 2 1 2 2 0 2 1 2 0 0 2 VVV V V fV 0 2 1 2 2 0 0 1 H k k VV VV VV VV 3 k VV VV VV c f VV mp P.M. 3 (2) (2) 2 0 3 (2) (2) 2 0 x x x E 28 gggg I T A B k bPPR f VV VVV VVV VVV bPP f VVV VVV VVV f V f V V z V 2 3 0 3 4 0 3 4 0 3 4 0 3 4 sl. k bPPR f VV VVV VV VV 2 3 0 3 4 3 4 E 0 0 1 0 0 1 3 VV k VV VV f V VV V V V V VV k VV V V 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 3 k V V 0 0 0 0 1 H A7 24 gg Igg c fV V V V V f VV V VV V f f VV u V fV k f VVV k VVV VV VV P.M. k VVV VVV k VVV 0 0 1 k aPR gVVV VVV f V VVV V 3 4 0 3 sl. k V V V V V 0 0 0 p 0 0 1 2 VV k VV VV f V VV 9 VV k V V V V 8 V 0 0 1 0 0 DRIFTING BLUES - Eric Clapton of 5 C Verse T 16 k bPPR f VV VVV VV VV gggg 6 I 8 bPP f VV VVV VV f V f V V z V V mf T A B 20 gggg I T A B 2 3 0 0 3 4 3 4 0 3 0 3 2 3 sl. 0 k VVV VVV f V VVV k 0 0 1 3 0 0 1 0 0 1 0 0 1 0 0 1 3 0 0 1 0 Generated using the Power Tab Editor by Brad Larsen. ![]() B Pre-Verse 12 gggg f VVV V V P I z V fV V T A B 0 3 4 0 V 0 4 2 sl. V 0 0 1 VV V bPP f VV VV VV VVV V V z V 0 0 1 0 2 0 2 3 0 3 4 0 3 0 3 0 3 4 0 0 sl. 8 k V H V k V k f VVV V V fV c V cV V fV mp tr [[[[[[ H 5 V V V 0 0 1 3 0 0 1 sl. ![]() DRIFTING BLUES As recorded by Eric Clapton (From the 1994 Album FROM THE CRADLE) Transcribed by Kwak Words an Williams A Intro P = 100 E 1 gggg 6 I 8 fV V Gtr I T A B k R V k V aP V f tr gggg I V [[[[[ tr T A B 0 (2) 0 c V V fV 2 V [[[[ 0 0 0 0 (2) 2 2 2 0 (2) 0 0 0 0 0 0 2 2 R V k V aP c V 0 gggg 6 I 8 V k VVV VVV f V VVV 0 0 1 T A B 0 0 1 0 0 1 3 2 0 0 0 2 2 0 98 bPP f VV VV VV VVV V V P f V f V V z z 0 0 0 2 3 3 4 0 3 0 3 0 3 4 0 0 4 2 0 0 VV k VV VV f V VV V V V V VV k VV V V 0 0 1 0 0 1 0 0 1 V 0 sl. ![]() 90 day plan for interview template3/21/2024 ![]() ![]() In his popular book “The First 90 Days on the Job-Proven Strategies for Getting up to Speed Faster and Smarter” by Michael Watkins, he recommends preparing for the new role before stepping onto the company’s grounds. The 90-day planning process helps to set the stage for a successful transition. By creating this asset for yourself before you begin your new role, you will increase the chances of achieving your goals with clarity and confidence. The onboarding process is often geared toward the benefit of the company. The outgoing CEO, the chief human resources officer, and the board should all have roles in helping the newcomer navigate company culture and politics."īut that’s for the benefit of the organization. Meanwhile, boards and key executives fail to grasp the complex nature of CEO succession or set one-dimensional expectations of the new leader.Ī comprehensive succession process begins when a candidate accepts the position and lasts for several months after his or her arrival. "Newcomers (new CEOs) misread the political situation or overestimate the organization’s willingness to abandon old behaviors. ![]() In the Harvard Business Review article, After the Handshake by Dan Ciampa, one-third to one-half of new CEO's, whether they're hired from outside or internally, fail within their first 18 months. Up to 50% of new CEOs fail within 18 months The 90-day plan is dual purposed (1) for job interview preparation and (2) as your ready-made onboarding and training plan for your new opportunity. This article examines the onboarding process for new CEOs and provides a 90-day plan sample for your use. Whether you’re currently interviewing for a C-level role or have just accepted a new role as a CEO, this 90-day plan will help you transition into your role much faster and with greater harmony. It includes operational planning for finance, human resources, operations, and environmental health and safety (EH&S). You can easily apply the principles to any business. The following 90-day plan is based on a manufacturing operation. 90 Day Plan for a manufacturing operation Both your board and your team will appreciate your thoughtfulness and planning prowess, while you simultaneously raise your visibility and strengthen your personal brand as an astute business leader. It will also eliminate the last-minute scramble to pull your quarterly reporting numbers together. It’s a valuable tool to keep you and your team on track. The plan is sure to keep you and your team on track and accountable.Ī 90-day plan helps to document, organize and create an action plan for the next quarter. For your continuous improvement plan at any level: Create the plan and use it in perpetuity.This prowess demonstrates your planning skills as well as your business acumen. The board will certainly be impressed when you present them with your own productivity plan. For your first 90 days on the job as the CEO: The 90-day plan can be used to help you onboard and ramp up faster and it also serves as your training plan.Although you will need to make a few assumptions to complete the plan, the 90-day plan becomes your job interview pitch deck (refer to the PDF download template at the end of this post). What better topic to speak about than your coveted company itself. Most candidates struggle with a proposed topic. Often candidates are asked to deliver a presentation on a topic of their choice. ![]()
Will a notarized letter of guardianship3/21/2024 ![]() “In the event of an emergency, we grant permission for him/her to make decisions about medical, dental, educational and recreational circumstances for our child. Include situations you hope don’t happen, like emergencies. Be very specific about what they’re allowed to do while they care for your child. Next, you grant certain powers to the guardian. With a temporary guardianship, it isn’t usual for there to be an exchange of money. You won’t need to list anything like how much child support you agree to. ![]() This legal document authorizes Hiram Earhart, her grandfather, to serve as temporary legal guardian of Genevieve from March 2, 2019, to April 14, 2019.” Include the specific dates the agreement begins and ends.įor example, “We, Amelia and Peter Earhart, are the parents of Genevieve Earhart, and we have legal custody of her. In the “Statement of Consent,” name yourself as the child’s current guardian and then name the person to whom you give guardianship. Always follow a formal salutation with a colon (:), not a comma. Use something like “To Whom It Concerns:” or “Dear Sir or Madam:”. The formal salutation (or greeting) is another two lines down. The subject should say “Re:” (it stands for “Regarding”) and then “The Guardianship of” followed by the child’s full name. Two lines down are the subject and the greeting. ![]() List their full name and address like you did for the parents above. The next block is about the intended guardian, who is also the letter’s recipient. Then two lines down put the date the letter will be signed. The parents’ information goes first, with their full names and addresses. In the letter heading, include basic details like names and addresses. It’s easy if you follow these simple steps. If you must leave for an extended stay, you face a jail sentence or you can’t care for the child for other reasons, a temporary guardianship letter is needed. Most of the time, you’d give only temporary guardianship, not permanent. If you make the decision to give custody of your child to someone you trust, you need to write a guardianship letter. ![]() Are you seeking legal guardianship of a minor? Click here for a go-to legal guardianship letter to use as a guide! ![]() Color by number for adults flowers3/21/2024 ![]() There are templates/backgrounds you can color and freehand on - you can also important your own drawings (and I could color on those without paying). You also have a freehand marker you can use as part of that, meaning you can draw or accent anywhere on the coloring page, not just where the app wants you to. The best part is that you have seven tools and brushes, which at this point is hard to find in any other app. I like the pages that they have available for free.Īs soon as you open an image, they give you a suggestion for how to color it (briefly) as well as a link to inspiration in a gallery. While I love it, I also love the purist coloring apps, of which this is one.Īt the time of this writing there are 18 free pages available, and hundreds more you can get with a subscription. I am so pleasantly surprised with this app! As I mentioned, a lot of the apps have turned into color by number. Given how much you get for free, I consider this to be a free app if you don't mind ads. There were some full screen ads when I went into various coloring pages, and they weren't too annoying. Subscription - I tried to figure out where I would pay in this app, but the only thing I could find was removing ads for $7.99. The app determines it for you - there's no thought required. Sometimes you'll be coloring with with ombre, and other times you're coloring with a design. There's also Disney, Marvel, and some other big characters you'll recognize. There are 15,000 designs that are free in more than 15 categories: animals, flowers, places, hobbies, mandalas and more. And that's exactly what you'll do with this app. Sometimes you don't want to pick the colors, but you want them picked for you. This is called a color by number "game," but really it's less of a game and more of a "pick the color and then fill in the corresponding area by tapping it." But that shouldn't take anything away from the mindless coloring that this game affords. Take a peek and let me know what you think! I also really like Chroma because of the value for what you get. If you commit to free and don’t want a subscription, you’ll have to watch a lot of ads.Īfter reviewing these adult coloring apps, I like them all – but Pigment and Happy Color® are my DEFINITE front runners (reviews below).
![]() NOTE: Add 25 percent premium for Third Models chambered for. A Deluxe version was offered, with fancy walnut checkered stock, straight-/pistol-grip with grooved slide handle. Distinctive feature of Third Model is locking cut made on the front top of receiver to allow breech-bolt to lock externally. Serial numbered from 325251 to as high as 853000 (numbered on both lower tang and bottom front of receiver). Third Model (Take-down): 24" octagon barrel blued frame adjustable rear sight. A Deluxe version was offered, with fancy walnut checkered straight-/pistol-grip stock and grooved slide handle. If you would like to obtain factory research on your. Those dates coincide with the Madis dates and can be viewed on Winchester’s site at:. While manufactured only two years apart (18. ![]() These blued frame Second Models are much more numerous than case-hardened variety. For purposes of determining if your gun is legally considered an antique (pre-1899 DOM), the BATF has told us they use the DOM dates published by the manufacture (Winchester). Model 1890 fans will immediately recognize these guns as Second Models with the takedown screw visible on back of the case-colored receiver. Serial numbered from 112971 to 325250 (on lower tang until 232328, then on bottom front end of receiver). Second Model (Blued Frame Variation): same as above, with blued frame. A Deluxe version was offered, with fancy walnut checkered straight-/pistol-grip stock and grooved slide handle. These Second Model guns feature same concealed locking lugs, with added take-down feature. Serial numbered from 15553 to 112970 (on lower tang only). Second Model (Take-down): 24" octagon barrel case-hardened frame adjustable rear sight. Their distinctive feature is concealed locking lugs and solid-frame. Approximately 15,552 First Model guns produced. First Model: solid-frame 24" octagon barrel case-hardened frame fixed rear sight. Model 1890 came in three separate and distinct variations that greatly affect value: 1. Produced from 1890 to 1932, with approximately 775,000 guns sold. Secure an expert appraisal before proceeding. Winchester offered many extra-cost options for this rifle that will greatly affect value. ![]() One of Winchester's best selling small caliber firearms and in worldwide use. The new value of a WINCHESTER 94 rifle has risen 59.13 dollars over the past 12 months to a price of 1,273.77. All Model 1890s were furnished standard with plain walnut straight stocks, with crescent buttplate and 12-groove slide handle. The 12 month average price is 1,335.94 new and 940.61 used. This rifle was slide-action top ejecting, with an 18" under barrel magazine tube. 22 Short, Long and Winchester Rimfire cartridges (WRF cartridge was developed by Winchester specifically for Model 1890) not on an interchangeable basis. WACA members who are also CFM Members will receive 15 additional record searches on top of the regular quantity of searches included in the standard CFM membership package, regardless of membership level.Model 1890 was the first slide-action rifle ever produced by Winchester. If you would like to obtain factory research on your Winchester, we urge you to join WACA and the Cody Firearms Museum. ![]() Those dates coincide with the Madis dates and can be viewed on Winchester’s site at: For purposes of determining if your gun is legally considered an “antique” (pre-1899 DOM), the BATF has told us they use the DOM dates published by the manufacture (Winchester). This information is no substitute for obtaining a Winchester Factory Letter from the Cody Firearms Museum (available for certain models and serial ranges) which in addition to the Serial Number Application Date, normally provide the original Received In Warehouse Date and Date Shipped from Winchester factory. George Madis, Ned Schwing, etc.), in which case the data was extrapolated to the best of our ability. To the maximum extent possible, the dates of manufacture shown were obtained from the original Winchester Factory Polishing Room serialization records otherwise estimates were made using multiple sources of information (e.g. ![]() Jenny glam nude teen3/20/2024 ![]() “I’m actually pretty puffy today.SexCams xXxVideos JJGirls Milf R18 BigTits JavGallery JavPictures JavPornhub Daisy Watts Karla Kush Madison Rose Persia Monir Anissa Kate Felicia Clover Nacho Vidal Holly Garner Kelly Madison Tracy Lindsay Emily Pink Sheila Marie Naomi Russell Chloe Amour Vicki Chase Tia Tanaka Eve Sweet Sara Bell Cadence Lux Jade Valentine Hilary Craig Alicia Williams Rinna Ly Alyssa Lynn Sara Stone Danielle Derek Gina Devine Brittany Oconnell Olivia Austin Alanah Rae Emiri Momota Tori Black Sammie Daniels Nala Brooks Amara Romani Ginebra Bellucci Danny D Alison Tyler Julia North Sean Lawless Madison Morgan Anie Darling Alice Green Anna Bell Peaks Shay Sights Jenna Jameson Kathy Anderson Ashley Blue Keira Blue Aubrey Black Denisse Gomez Odette Delacroix Erica Lauren Margo Sullivan Nicole Graves Ryan Ryans Franziska Facella Rocco Siffredi Janice Griffith Karina Hart Kelli Mccarty Demi Lopez Eva Long Codi Vore Foxy Alissa Charlee Chase Flower Tucci Coco Lovelock Lisey Sweet Aali Kali Anya Olsen Lanny Barbie Unlock Pix And Video Erotic Babes Pornpics Pixandvideo Jenny Glam Lovest European Tiava Sexo Pics Models Studios Categories Pornstars Channels Tags Rooms Scoreland Nfbusty Brazzers NaughtyAmerica XLgirls MatureNL Julesjordan Aziani Pornfidelity Evilangel Devilsfilm Hustler Spizoo RK Perhaps it was a puffy day,” she says, dabbing under her eyes. Everyone said I should visit Ray Stark – see what he might be up to. Ray Stark, the Hollywood producer behind Funny Girl, the riotous 1968 musical that made a star of Barbra Streisand, told Agutter she should have the bags done under her eyes. I think that’s beginning to fade, although there is still a desire to get plastic surgery – which isn’t my thing, only because I’m squeamish.” And that may be an issue rather than the fat-thin issue because we see people of all shapes and sizes. “I think there’s pressure on women in film to be young. She brushes it off as him “playing practical jokes”, but there must have been a huge pressure to be thin. He did make some comment about ‘Be careful about putting on weight’ particularly when I’m talking to journalists about dieting and how I keep fit.” And when I did interviews, he would send cakes to the tables as though I was going to eat masses of stuff. “He pointed out that my knees were getting fat,” she says. I may have been very lucky.” She screen-tested for Logan’s Run about six months after moving to the US – the only sexism she experienced was from its producer Saul David. The fact these scenes have now been reduced to rogue screengrabs for people’s titillation, she says, makes “my heart sink … It makes it bigger than it is.”ĭid she have any casting couch horror stories, I ask? “Nothing like that. And as Nurse Price in the Oscar-winning An American Werewolf in London (1981) – which she once called “perfect fantasy fodder” – she has sex in her shower with the American tourist she’s fallen for, unaware he’s about to turn into a werewolf at the next full moon. Later, she played the sexually provocative twentysomething stable girl Jill Mason in Equus (1977), where she stripped off fully naked for a troubled boy with an unhealthy obsession with horses – a role that earned her a Bafta. There was the skinny-dipping scene in Nicolas Roeg’s Walkabout (1971), filmed when she was just 16 it turned her into a pin-up, as the teenage girl lost in the Australian outback. Now, she explains, “ ended up out of context” on the internet. ![]() ![]() You can end up naked in places you don’t want to.” We’ve met up in a London hotel to discuss her new film, the decidedly not X-rated The Railway Children Return, but conversation has veered towards the nude scenes she did as a young actor. ![]() “It’s not an issue with me,” says the star of BBC’s Call the Midwife, in her softly spoken cut-glass accent. Jenny Agutter is talking to me about getting naked. ![]() Boxing ring near me3/20/2024 ![]() ![]() The ascension of King Chulalongkorn (Rama V) to the throne in 1868 ushered in a golden age not only for Muay but for the whole country of Thailand. This type of match was called Muay Khat Chueak (มวยคาดเชือก).ġ9th century Muay Boran during the reign of King Chulalongkorn Eventually, the previously bare-fisted fighters started wearing lengths of hemp rope around their hands and forearms. These Muay contests gradually became an integral part of local festivals and celebrations, especially those held at temples. As well as being a practical fighting technique for use in actual warfare, Muay became a sport in which the opponents fought in front of spectators who went to watch for entertainment. Muay Boran and therefore Muay Thai, was originally called by more generic names such as Toi Muay or simply Muay. An exhibition of Muay Thai was observed and reported by Simon de la Loubère, a French diplomat who was sent by King Louis XIV to the Kingdom of Siam in 1687, in his famous work and the Ayutthaya Kingdom Burmese–Siamese War (1765–1767). Muay Thai is believed to have been developed by the Siamese army as a form of self-defence and it can be traced at least to the 16th century as a peace-time martial art practised by the soldiers of King Naresuan. Some believe that Muay Thai ultimately originated from the Khmer pre- Angkorean martial art Bokator, while others maintain it originated in Thailand. The origin of Muay Thai is subject to scholarly debates. History Local school children in Thailand demonstrate Muay Thai. Western practitioners in Thailand are sometimes called Nak Muay Farang, meaning "foreign boxer". A practitioner of Muay Thai is known as a Nak Muay. Muay Thai is related to other martial art styles such as Muay Chaiya, Muay Boran, Muay Lao, Lethwei, Benjang and Tomoi. The professional league is governed by The Professional Boxing Association of Thailand (P.A.T.), sanctioned by The Sports Authority of Thailand (S.A.T.). Muay Thai became widespread internationally in the late 20th to 21st century, when Westernised practitioners from Thailand began competing in kickboxing and mixed-rules matches as well as matches under Muay Thai rules around the world. This discipline is known as the "Art of eight limbs", as it is characterised by the combined use of fists, elbows, knees and shins. Muay Thai ( Thai: มวยไทย, RTGS: muai thai, pronounced ⓘ), sometimes referred to as Thai boxing, is a combat sport that uses stand-up striking, sweeps, and various clinching techniques. ![]() Telegram channel porn3/20/2024 ![]() ![]()
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